Styling Header
To set style for a specific cell of the header you should use the following technique:
General styling of the header
<style> .my_style{ background-color:#FFAAAA; }</style>
<script>webix.grid({ columns:[ { id:"title", header:{ text:"Film title", css:{ "background":"#AFA"}} }, { id:"votes", header:{ text:"Votes", css:"my_style"} } ]});</script>